Electrical conductivity increase by order of magnitude through controlling sintering to tune hierarchical structure of oxide ceramics

نویسندگان

چکیده

Perovskite calcium manganate CaMnO3-δ is representative of an essential group semiconductors with unique physical phenomena including colossal magnetoresistance and thermoelectric properties. For the large-scale applications that require utilization oxide ceramics, polycrystalline materials’ properties such as conductivity can be controlled ultimately optimized through tuning ceramics sintering conditions. In present study, impact temperature on structure performance systematically studied. pellets made precursors powders synthesized using chemical sol-gel reaction, increase in dramatically increases electrical by order magnitude simultaneously Seebeck coefficient. Meanwhile, thermal rise temperature. Among samples sintered at different temperatures, peaking Figure Merit ZT pristine reached 0.28, which a factor 2.5 higher than highest reported for approached doped single-phase CaMnO3-δ. The changes were interpreted based hierarchical evolutions, from unit cell level to micron scales, induced temperatures.

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ژورنال

عنوان ژورنال: Journal of Solid State Chemistry

سال: 2021

ISSN: ['0022-4596', '1095-726X']

DOI: https://doi.org/10.1016/j.jssc.2020.121831